`Exploring unique functions from the "Interface"`

@It is a common knowledge in recent research that "surface and bulk are different". However, then what is the differencebetween a surface or interface and a bulk?
@ When defining a surface or interface, there is always an "orientation". In the case of a water  surface, the upper part is airand the lower part is bulk water, and the boundary between these  two media is defined with the "water surface" or the "air-water interface". The orientation of the  molecules at the interface affects a wide variety of physical properties andfunctions,  such as hydrophilicity/hydrophobicity, adhesion, biocompatibility, and friction, etc.

@Sum-frequency generation spectroscopy is a unique method to selectively observe the behavior of molecules at surfacesand interfaces by using the specific light generated at the interface  between different media when the target sample isirradiated with two short laser pulses of  different wavelengths.

@The goal of this laboratory is to use various spectroscopic techniques to elucidate the  relationship between molecules andvarious micro- and macroscopic phenomena occurring at  surfaces and  interfaces, such as hydrophilicity, water repellency,friction, biocompatibility,  adhesion, delamination, molecular adsorption, liquid interfaces, and charge accumulation/transport phenomena inside the cutting-edge of the organic devices.
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If you are interested, please contact  Prof. Miyamae


Topics@@@@@@@@@@@@@@@     @@   last update; 2024/04/10

EMember page updated (2024/4/1) ΛMembers

EInterfacial Phenomena in Adhesion and Adhesive Bondingis published fromSpringer-Nature.Open Accessbook.(2023/10/30)Editors: S. Horiuchi, N. Terasaki, T. Miyamae
  Chapter 5, "Analysis of Molecular Surface/Interfacial Layer by Sum-Frequency Generation (SFG) Spectroscopy"
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2023/9/12  Koki Tanoue presented in 17th Annual Meeting of Japan Society for Molecular Science 2023(Osaka Univ.,2023/9/12~15). ->photo
@@Relationship between Molecular Orientation at the Organic Semiconductor Interfaces and their transistor characteristics,›Koki Tanoue,Masaki Tomita, Hisao Ishii, Takayuki Miyamae




2023/9/12  Ryosuke Obuchi presented in 74th Divisional Meeting of Division of Colloid and Surface Chemistry(ShinsyuUniv.,  2023/9/12~15). ->photo
@@Emulsifier-induced changes in the molecular behavior at coconuts oil interface,Z Ryosuke Obuchi,Yoshihide Kagiyama,Wataru Kaneko,Tomohito Hanazawa, Takayuki Miyamae




2023/9/11  Seito Yamazaki presented in EUROADH/WCARP(Germany,  2023/9/10~13). ->photo
@@Curing Mechanism at the Polyurethane Adhesive Interface: Differences in Reactive Properties in the Bulk and at the Interface,Z S.Yamazaki and T. Miyamae




2023/7/18  Seito Yamazaki presented in The 13th SPSJ International Polymer Conference (Sapporo). ->photo
@@21P060b  Difference in Curing Behavior between Interface and Bulk in Urethane Adhesives,Z S. Yamazaki and T. Miyamae




2023/6/22  K. Morimoto presented in 36th Japan OLED forumD
@@S4-3  Analysis of Top-Emission Organic Light-Emitting Diode using Electric-Field-Induced Doubly Resonant Sum-Frequency GenerationVibrational Spectroscopy,ZK. Morimoto, T. Kaburagi, H. Ohata, S. Noh, T. Miyamae




2023/6/7@Our paper is publishes inOrganic Electronics.
"Operando measurements of top-emission organic light-emitting diode using electric-field-induced doubly resonant sum-frequencygeneration vibrational spectroscopy", K. Morimoto, T. Kaburagi, H. Ohata, S. Noh, and T. Miyamae, Organic Electronics, 120 (2023) 106862.DOI:10.1016/j.orgel.2023.106862



Our review paper is published atOleoscience.(written in Japanese).
@gMolecular Behavior at Liquid Interfaces Investigated by Sum-Frequency Generation Spectroscopy (written in Japaneseh, T. Miyamae,Oleosciense, 23, 199-206 (2023).@
       



2023/4/3  Member page updated ΛMembers



2022/02/10  Koki Tanoue presentedAjou-Chiba University Joint sympojium(Chiba University)D->photo
@@Molecular rearrangements at the Indigo/TTC interface and their relationship of semiconductor ordering,Z K. Tanoue, H. Ishii, T. Miyamae




2023/1/20@Our paper is published inApplied Physics Express.
"Electrostatic charges and their distribution on the charged surfaces probed by
sum-frequency generation spectroscopy",Y. Isaka and T. Miyamae, Appl. Phys. Express,2023,DOI:10.35848/1882-0786/acb1ec.



2022/12/5  Invited talk at theFuture Light Innovation Research Area Meeting(Saitama University)
@@Interface Analysis by Sum Frequency Generation and its Application to Practical Materials,Z T. Miyamae




2022/9/23  Congratulation! Yui Suzuki won the  Student Award of ALC'22
@@18P-02,Study of the lubricants on polypropylene surfaces by using SFG vibrational spectroscopy,ZY. Suzuki, H. Sakai, N. Aoki, and T.Miyamae




2022/9/22  Yui Suzuki perticipated 73th Colloid and Surface Chemistry Meeting @ Hiroshima Universitu. ¨Photo
@@3D03,Study of lubricant molecules on polymer films by SFG spectroscopy,ZY. Suzuki, A. Sakai, N. Aoki, and T. Miyamae




2022/9/22  Kouki Tanoue perticipated 83rd JSAP fall Meeting@Tohoku University. ¨Photo
@@22a-C106-1,Study on organic thin-film transistors and film structures using Indigo,ZK. Tanoue, Y. Tanaka, H. Ishii, and T. Miyamae




2022/9/19-22  T. Miyamae & our students attended to the16th Annual Meeting of Japan Society for Molecular Science. ¨Photo

1D07 Origin of Surface Charging by Sum Frequency Spectroscopy and Non-
contact Visualization
ZT. Miyamae and Y. Isaka

1p046 interfacial structure of saponins by sum frequency generation spectroscopy ZY. Kagiyama and T. Miyamae

2p041 Evaluation of Molecular Structure of Surface Alkyl Groups of LiquidRepellent Films by SFG ZR. Mizuno, C. Urata, K. Watanabe, A.
Hozumi, and T. Miyamae

4p045 Analysis of OFET interface using SFG spectroscopy ZT. Isobe and T. Miyamae



2022/9/9  Yuuka Isaka attend the Annual Meeting of IESJ.
@@9pA-1  Observation of Charging Phenomena in Polypropylene by SFG Spectroscopy,ZY. Isaka and T. Miyamae




2022/8/8  Online lecture at  Yumenabi Web page.  
      What is "Yomenabi"H



2022/7/30  Invited talk at 40th Kansai Interface Science seminar (ZOOM On-line)



2022/7/20@Our paper is published at J. Raman Spectroscopy.
"Interface structure of escin at air-water interface probed by sum frequency generation spectroscopy",Y. Kagiyama and T. Miyamae,J. RamanSpectrosc.,2022,DOI: 10.1002/jrs.6418.





Joint Seminar was held by 4 laboratories in Kanto region. 11th May, 2022 @Chiba University

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@In-hause meeting was held at Chiba University.
Ouchi lab (Tokyo Tech), Miyamae lab. (Chiba Univ.) Tsukuba Univ. (Ishibashi lab.) Saitama Univ. (Yamaguchi lab.)Λ@Program.pdf@


2022/3/17@Our paper is published at Solids.
"Evaluation of the Molecular Conformation of Surface Alkyl Chains of Alkylsilane-Derived Hybrid Films Using Sum-Frequency GenerationSpectroscopy",R. Mizuno, C. Urata, K. Watanabe, A. Hozumi, and T. Miyamae,  Solids,3, 147-154 (2022),DOI: 10.3390/solids3010010.



Lecture video is now available on theChemstation YouTube Channel(2022/02/09)
 



Our review paper is published at "Review of Laser Engineering" (written in Japanese).
@"Charge Carrier Behavior of the Organic Devices Using Operando Sum-Frequency Generation Spectroscopy"T. Miyamae,Review of Laser Engineering,50, 17-21 (2022).



Perticipated  The 9th International Symposium on Surface ScienceiDec. 1, 2021 Onlinej
@@01PS-5 Air-Water Interface Structure of Saponin by Sum Frequency Generation Spectroscopy,   ZY. Kagiyama and T. Miyamae

@@01PS-9Evaluation of the Molecular Conformation of Surface Alkyl Groups of the Liquid-Repellent  Films using SFG, ZR. Mizuno, C. Urata, K.Watanabe, A. Hozumi, and T. Miyamae




Talk at the  Q ColioquiumiNov. 29, 2021, Online)
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Online meeting withKatsumata Groupat UMASS Amherst Polymer Science and Egineering Dept. (Sep. 16, 2021)
 

 Web site link: Katsumata Research Group at UMASS Amherst



Talk at the M&BE of JSAP (Sep. 9, 2021, Online)
 M&BEV•ͺ–μŠJ‘ρŒ€‹†‰ο2021u—L‹@ή—ΏEƒfƒoƒCƒX’†‚Μƒ_ƒCƒiƒ~ƒNƒX ‚π’T‚ιŒv‘ͺ‹Zp‚̍őOόv



Our paper is published at Journal of the Society for Information DisplayD
"Operando sum]frequency generation spectroscopy of high]efficiency OLEDs for probing the charge carrierbehavior",T. Miyamae and T. Sato,J. Soc. Inf. Display, 2021, 1-12(2021),DOI: 10.1002/jsid.1076




Our review paper is published at "Bunseki" (written in Japanese).
@"Interface analysis by nonlinear spectroscopy" T. Miyamae,‚Τ‚ρ‚Ή‚«, 2021”N8†, 363-371.@
                               



New B4 students are joined with our group (Apr. 1, 2021) ΛMembers



Invited talk atKPS spring meeting(Apr. 21-23, 2021 Online)



Our review paper is published at "Keisoku-to-Seigyo" (written in Japanese).
"Operando Analysis of the Organic Devices by Sum-Frequency Generation Spectroscopy",T. Miyamae.



Our paper is published at ACS Applied Materials & Interfaces asCover articleD
"Role of Chemical Functionality in the Adhesion of Aluminum and Isotactic Polypropylene",Y. Liu, Y. Shigemoto, T.Hanada, T. Miyamae, K. Kawasaki, and S. Horiuchi,ACS Appl Mater. Interfaces.,13, 11497-11506 (2021),DOI: 10.1021/acsami.0c22988
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Our paper is published at PCCP
"Direct imaging of Electric field behavior in 2,7-Diphenyl[1]benzothieno[3,2-b][1]benzothiophene Organic Field-Effect transistors by Sum-Frequency Generation Imaging Microscopy", CDKatagiri, T. Miyamae,.H. Li, F. Yang, andS. Baldelli,Phys. Chem. Chem. Phys.,23, 4944-4950 (2021).DOI: 10.1039/D0CP06407F




Our paper is published at Organic Electronics
@"Relationship between the surface structure of the gate insulator and the performance of  organic thin-filmtransistors",C. Katagiri, K. Akaike, T. Miyamae,Org. Electronics, 2020,86, 105928.




New lab is started at Chiba University (Jul. 1, 2020)@¨@Access